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ir.bowen.edu.ng:8181/jspui/handle/123456789/2847| Title: | Crystal structure of tricarbonyltris(pyridine-κN)rhenium(I) tetrafluoridoborate |
| Authors: | Ikotun, A. A. Coogan, M. P. Owoseni, A. A. Bhuvanesh, N. Egharevba, G. O. |
| Keywords: | crystal structure rhenium(I) tricarbonyl complexes tricarbonyl tris-pyridyl rhenium(I) cation luminescent agent |
| Issue Date: | 2015 |
| Citation: | Ikotun, A. A., Coogan, M. P., Owoseni, A. A., Bhuvanesh, N., & Egharevba, G. O. (2015). Crystal structure of tricarbonyltris(pyridine-κN)rhenium(I) tetrafluoridoborate. Acta Crystallographica. Section E, Crystallographic Communications, 71(Pt 5), m106–m107. |
| Abstract: | In the title compound, [Re(C6H5N)3(CO)3]BF4, the Re1 ion is six-coordinated by three pyridine N atoms and three carbonyl C atoms. In each case, the carbonyl C atom lies trans to a pyridine N atom. In the crystal, the ions are linked via C—H F hydrogen bonds and C—H π interactions, forming a three-dimensional framework. The F atoms of the BF4 anion are disordered over two positions and gave a final refined occupancy ratio of 0.705 (11):0.295 (11). |
| URI: | ir.bowen.edu.ng:8181/jspui/handle/123456789/2847 |
| Appears in Collections: | Articles |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Cystal Structure Page 87.pdf | 382.58 kB | Adobe PDF | View/Open |
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